Abstract
In this study we prepared a poly(lactic acid)/ethyl cellulose (PLA/EC) bioplastic blend film by melt pressing after solvent casting and investigated the optical, thermal, and mechanical properties in relation to the structural changes revealed by various microscopies and scattering measurements. Despite the immiscibility of PLA and EC, the blend film exhibited good optical transparency due to the close match in their refractive indices. A second run of differential scanning calorimetry during heating revealed a decrease in the glass transition temperature () and melting point (
) of PLA with EC although EC had the higher values. Thermomechanical analysis suggested that these decreases were due to the negative pressure generated due to the suppression of PLA shrinkage below
and above
during cooling. Furthermore, ductile drawing of the blend film (70/30) at an optimal temperature of 70 °C above
resulted in a uniform whitening near 100% strain. Delamination at the interface between the PLA matrix and EC domain led to the formation of micrometer-sized oriented voids, which enhanced the refractive index difference in the phase-separated structure, thereby scattering light and achieving the uniform and oriented white blend film.
Acknowledgements
The author would like to thank Mr. Tetsuhiro Kunikiyo for collaboration in preliminary experiments. This work was financially supported by JSPS KAKENHI Grant Number JP21K05204.
Disclosure statement
The author declares no competing financial interest.