Circular dichroism spectra of a series of 4-(tetra-hydroxy-tetryl-1-yl)-2-phenyl-2 H -1,2,3-triazoles were measured and the sign of their Cotton effects was correlated to the absolute configuration of the hydroxyl group to the triazole base moiety. Those having the D- glycero -configuration in their Fischer projection formula show positive Cotton effect and those with the L- glycero -configuration show negative Cotton effect. This correlation was extended for the assignment of the anomeric configuration of the corresponding glycofuranosyl- C -nucleosides.
- Choose new content alerts to be informed about new research of interest to you
- Easy remote access to your institution's subscriptions on any device, from any location
- Save your searches and schedule alerts to send you new results
- Export your search results into a .csv file to support your research