UiO-66 (Zr-MOF): Synthesis, Characterization, and Application for the Removal of Malathion and 2, 4-D from Aqueous Solution

ABSTRACT

UiO-66 (Zr-MOF) metal-organic framework was successfully synthesized by the solvothermal method and characterized using FTIR, PXRD and TGA. Its ability to remove Malathion, 2,4-Dichlorophenoxyacetic acid (2,4-D) and a mixture of the two from an aqueous solution was studied. Effects of different experimental parameters (pH, adsorbent dose, contact time, speed of agitation and initial pesticide concentrations) were studied. Adsorption isotherm study revealed that the equilibrium data well fitted the Freundlich, Langmuir and Jovanovic isotherm models. Similarly, the kinetics study showed that the pseudo-first-order model gave the best fitting. Thermodynamic study indicated that the adsorption process was spontaneous and exothermic. To evaluate the matrix effect, tap water samples were spiked with standard solutions of the analytes and recoveries in the range of 70–120% were obtained. Based on the findings of the present study, UiO-66 (Zr-MOF) could be taken as a promising adsorbent for the removal of pesticides from aqueous samples

KEYWORDS:

• Adsorption
• 2,4-D
• Malathion
• UiO-66 (Zr-MOF) metal-organic framework

Acknowledgments

The authors are very much grateful for the support of the Department of Chemistry, College of Natural and Computational Sciences, Haramaya University, Ethiopia.

Disclosure statement

No potential conflict of interest was reported by the author(s).

Data availability statement

No additional data have been used to support the findings of this study.