ABSTRACT
The polymer poly(BPA-phthalate) (BPA-PHTH) was synthesized from BPA and phthaloyl dichloride by using interfacial condensation polymerization. The prepared polymer was characterized using (FTIR,1H-NMR, 13C-NMR, DSC, TGA, SEM, and polymer solution viscosity. The characterization by 1H-NMR, 13C-NMR, and FTIR proved the suggested structure. The DSC shows that the polymer is not linear, while the TGA shows that it is thermally stable up to 350°C. SEM showed solid surface filled with pores. The polymer uptake behavior towards Pb(II), Cd(II), and Cu(II) ions was studied by the batch equilibrium technique as a function of pH and contact time. The metal-ion uptake by the polymer reached at pH = 6 a maximum of 92.59, 65.79, and 72.46 for Pb(II), Cd(II), and Cu(II) ions, respectively. The metal ion uptake properties of the polymer show fitting for Langmuir, Freundlich, and (D-R) isotherm equations. The experimental data fit to both the Langmuir and the Freundlich models (R2 > 0.99). Column experiments were used to determine the loading capacity and study the desorption of metal ions. The metal-bound polymer was regenerated by treatment with 0.1 M HNO3 for Pb(II) and Cd(II), while 0.5 M EDTA for Cu(II). Therefore, it may be employed for the removal of heavy metal pollutants in environmental and industrial applications.
Disclosure statement
No potential conflict of interest was reported by the authors.