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Original Articles

A Comprehensive Experimental Investigation of the Methyl Methacrylate/Butyl Acrylate/Acrylic Acid Emulsion Terpolymerization

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Pages 829-853 | Received 02 Dec 2002, Accepted 04 Jul 2003, Published online: 15 Feb 2007

References

  • Brandrup , J. and Immergut , E. H. , eds. 1989 . “ Physical constants of some important polymers ” . In Polymer Handbook , 3rd ed. New York : A Wiley‐Interscience Publication, J. Wiley & Sons .
  • Athey , R. D. 1991 . “ The monomers ” . In Emulsion Polymer Technology , Plastics Engineering Edited by: Hudgin , D. E. Vol. 22 , 59 – 109 . New York : Marcel Dekker, Inc. .
  • Bangs , L. B. 1984 . Uniform Latex Particles Seragen Diagnostics Inc. .
  • Barton , J. 1990 . Emulsion copolymerization kinetics with polar monomers . Makromol. Chem. Macromol. Symp. , 35/36 : 41 – 58 .
  • Capek , I. and Potisk , P. 1995 . Microemulsion and emulsion polymerization of butyl acrylate—I. Effect of the initiator type and temperature . Eur. Polym. J. , 31 ( 12 ) : 1269 – 1277 .
  • Chern , C. S. and Hsu , H. 1995 . Semibatch emulsion copolymerization of methyl methacrylate and butyl acrylate . J. Appl. Polym. Sci. , 55 : 571 – 581 .
  • Chern , C. S. and Lin , F. Y.J. 1996 . Stability of carboxylated poly(butyl acrylate) latices during semibatch emulsion polymerization . J. Appl. Polym. Sci. , 61 : 989 – 1001 .
  • Cutting , G. R. and Tabner , B. J. 1995 . Reaction temperature profiles and radical concentration measurements on batch emulsion copolymerizations of methyl methacrylate and butyl acrylate . Eur. Polym. J. , 31 ( 12 ) : 1215 – 1217 .
  • Cutting , G. R. and Tabner , B. J. 1997 . Radical concentrations and reaction temperature profiles during the (batch) core–shell emulsion polymerization of methyl methacrylate and butyl acrylate, studied by electron spin resonance spectroscopy . Eur. Polym. J. , 33 ( 2 ) : 213 – 217 .
  • Guillot , J. Computer simulation of microstructure and glass transition temperature of random copolymer . Proceedings of the Third Berlin International Workshop on Polymer Reaction Engineering . 1989 , Berlin. Polymer Reaction Engineering , Edited by: Reichert , K. H. and Geiseler , W. pp. 295 – 301 . New York : VCH Publishers .
  • Guillot , J. 1992 . “ Emulsion copolymer glass‐transition behavior and particle morphology ” . In Polymer Latexes: Preparation, Characterization and Applications , 1st ed. , ACS Symposium Series Edited by: Daniels , E. S. , Sudol , E. D. and El‐Aasser , M. S. Vol. 492 , 145 – 162 . Washington, DC : American Chemical Society .
  • Kammona , O. , Fratzikinakis , C. , Pladis , P. and Kiparissides , C. 2003 . A comprehensive experimental and theoretical investigation of the styrene/2‐ethylhexyl acrylate emulsion copolymerization . Macromol. Chem. Phys. , 204 : 983 – 999 .
  • Kine , B. B. and Novac , R. W. 1989 . “ Acrylic and methacrylic ester polymers ” . In Encyclopedia of Polymer Science and Engineering , 2nd ed. Vol. 1 , 234 – 299 . New York : A Wiley‐Interscience Publication, John Wiley and Sons .
  • Maxwell , I. A. , Napper , D. H. and Gilbert , R. G. 1987 . Emulsion polymerization of butyl acrylate. Kinetics of particle growth . J. Chem. Soc., Faraday Trans. , 83 : 1449 – 1467 .
  • Okaya , T. , Suzuki , A. and Kikuchi , K. 1999 . Importance of grafting in the emulsion polymerization of MMA using PVA as a protective colloid. Effect of initiators . Colloids Surf., A: Physicochem. Eng. Asp. , 153 : 123 – 125 .
  • Pedrosa , S. M.C.P. and Nunhez , J. R. 2000 . The behavior of stirred vessels with anchor type impellers . Comput. Chem. Eng. , 24 : 1745 – 1751 .
  • Plessis , C. , Arzamendi , G. , Leiza , J. R. , Schoonbrood , H. A.S. , Charmot , D. and Asua , J. M. 2000 . Seeded semibatch emulsion polymerization of n‐butyl acrylate, Kinetics and structural properties . Macromolecules , 33 : 5041 – 5047 .
  • Plessis , C. , Arzamendi , G. , Leiza , J. R. , Schoonbrood , H. A.S. , Charmot , D. and Asua , J. M. 2001 . Kinetics and polymer microstructure of the seeded semibatch emulsion copolymerization of n‐butyl acrylate and styrene . Macromolecules , 34 : 5147 – 5157 .
  • Poehlein , G. W. 1996 . Emulsion polymer reaction engineering . 27th Annual Short Course, Emulsion Polymers Institute, Lehigh University . June 3–7 1996 , Bethlehem, PA. Advances in Emulsion Polymerization and Latex Technology , Edited by: El‐Aasser , M. S. Vol. 1 ,
  • Sajjadi , S. and Brooks , B. W. 2000a . Semibatch emulsion polymerization reactors: polybutyl acrylate case study . Chem. Eng. Sci. , 55 : 4757 – 4781 .
  • Sajjadi , S. and Brooks , B. W. 2000b . Butyl acrylate batch emulsion polymerization in the presence of sodium lauryl sulphate and potassium persulphate . J. Polym. Sci. A: Polym. Chem. , 37 : 3957 – 3972 .
  • Sajjadi , S. and Brooks , B. W. 2000c . Unseeded semibatch emulsion polymerization of butyl acrylate: bimodal particle size distribution . J. Polym. Sci. A: Polym. Chem. , 38 : 528 – 545 .
  • Sayer , C. , Lima , E. L. , Pinto , J. C. , Arzamendi , G. and Asua , J. M. 2000 . Kinetics of the seeded semicontinuous emulsion copolymerization of methyl methacrylate and butyl acrylate . J. Polym. Sci. A: Polym. Chem. , 38 : 367 – 375 .
  • Tanrisever , T. , Okay , O. and Sonmezoglu , I. C. 1996 . Kinetics of emulsifier‐free emulsion polymerization of methyl methacrylate . J. Appl. Polym. Sci. , 61 : 485 – 493 .
  • Unzueta , E. and Forcada , J. 1995a . Semicontinuous emulsion copolymerization of methyl methacrylate and n‐butyl acrylate: 1. Effect of mixed emulsifiers in seeded polymerization . Polymer , 36 ( 5 ) : 1045 – 1052 .
  • Unzueta , E. and Forcada , J. 1995b . Semicontinuous emulsion copolymerization of methyl methacrylate and n‐butyl Acrylate: 2. Effect of mixed emulsifiers in unseeded polymerization . Polymer , 36 ( 22 ) : 4301 – 4308 .
  • Urretabizkaia , A. , Sudol , E. D. , El‐Aasser , M. S. and Asua , J. M. 1993 . Calorimetric monitoring of emulsion copolymerization reactions . J. Polym. Sci. Chem. Ed. , 31 : 2907
  • Urretabizkaia , A. , Leiza , J. R. and Asua , J. M. 1994 . On‐line terpolymer composition control in semicontinuous emulsion polymerization . AIChE J. , 40 ( 11 ) : 1850 – 1864 .
  • Yu , Z. Q. , Li , B. G. , Li , B. F. and Pan , Z. R. 1999 . Preparation and characterization of MMA–BA–DMAEMA terpolymer latex . Colloids Surf., A: Physicochem. Eng. Asp. , 153 : 31 – 38 .
  • Zhang , M. G. , Weng , Z. X. , Huang , Z. M. and Pan , Z. R. 1998 . Effects of monomer polarity on MMA/BA/NaMA emulsifier‐free emulsion copolymerization . Eur. Polym. J. , 34 ( 9 ) : 1243 – 1247 .

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