Effect of MgO on wetting and corrosion behaviour of corundum substrate by CaO–SiO₂–MgO (–Al₂O₃) slags

ABSTRACT

Effect of MgO content on wetting and corrosion behaviour of corundum substrate by CaO–SiO₂–MgO (−15%Al₂O₃) molten slags was investigated at 1450°C via joint application of a sessile drop technique, SEM–EDS detection and FactSage thermodynamic software. All slags exhibit good wettability on the substrate, and the contact angle values are small. Increasing MgO content from 7% to 9% in CaO-SiO₂-MgO slags can increase the contact angle between the droplet and the substrate, while the substrate dissolution thickness and the slag penetration depth tend to decrease. Increasing MgO content from 8% to 15% in CaO-SiO₂-MgO-15% Al₂O₃ slags can also increase the contact angle, but significantly decrease the slag penetration depth. The indirect dissolution thickness increases instead due to the formation of a large amount of MgAl₂O₄ by the interface reaction. The wettability can give an indication of the slag penetration depth in the substrate but not the dissolution thickness of the substrate.

KEYWORDS:

• Wetting
• corrosion
• MgO
• molten slag
• corundum
• sessile drop technique
• refractory,contact angle

Disclosure statement

No potential conflict of interest was reported by the author(s).

Additional information

Funding

The authors acknowledge the financial support of this study from the Young Elite Scientist Sponsorship Program by the China Association for Science and Technology (grant number YESS20200210).