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Polymer Reaction Engineering Volume 11, 2003 - Issue 4
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Original Articles

Mathematical Modeling of Multimonomer (Vinylic, Divinylic, Acidic) Emulsion Copolymerization Systems

M. Zubitur Institute for Polymer Materials (POLYMAT) and Grupo de Ingeniería Química, Departamento de Química Aplicada, Facultad de Ciencias Químicas, The University of the Basque Country, Apdo. 1072, Donostia‐San Sebastián, E‐20080, Spain
,
P. D. Armitage Institute for Polymer Materials (POLYMAT) and Grupo de Ingeniería Química, Departamento de Química Aplicada, Facultad de Ciencias Químicas, The University of the Basque Country, Apdo. 1072, Donostia‐San Sebastián, E‐20080, Spain; Infineum UK Ltd, Oxfordshire, United Kingdom
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S. Ben Amor Institute for Polymer Materials (POLYMAT) and Grupo de Ingeniería Química, Departamento de Química Aplicada, Facultad de Ciencias Químicas, The University of the Basque Country, Apdo. 1072, Donostia‐San Sebastián, E‐20080, Spain; Department of Chemical Engineering, University of Delaware, Newark, Delaware, USA
,
J. R. Leiza Institute for Polymer Materials (POLYMAT) and Grupo de Ingeniería Química, Departamento de Química Aplicada, Facultad de Ciencias Químicas, The University of the Basque Country, Apdo. 1072, Donostia‐San Sebastián, E‐20080, Spain
&
J. M. Asua Institute for Polymer Materials (POLYMAT) and Grupo de Ingeniería Química, Departamento de Química Aplicada, Facultad de Ciencias Químicas, The University of the Basque Country, Apdo. 1072, Donostia‐San Sebastián, E‐20080, SpainCorrespondence[email protected]
Pages 627-662 | Received 15 Oct 2002, Accepted 04 Jun 2003, Published online: 15 Feb 2007

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Ali Safinejad, Saeed Pourmahdian & Behzad Shirkavand Hadavand. (2020) Emulsifier-free emulsion polymerization of acrylonitrile-butadiene-carboxylic acid monomers: a kinetic study based on polymerization pressure profile. Journal of Dispersion Science and Technology 41:2, pages 157-167.
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Articles from other publishers (18)

Shaghayegh Hamzehlou, Aitor Barquero, Amaia Agirre, Fernando Ruipérez & Jose Ramon Leiza. (2023) Shedding Light on the Microstructural Differences of Polymer Latexes Synthesized from Bio-based and Oil-based C8 Acrylate Isomers. European Polymer Journal, pages 112410.
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Miren Aguirre, Nicholas Ballard, Edurne Gonzalez, Shaghayegh Hamzehlou, Haritz Sardon, Marcelo Calderon, Maria Paulis, Radmila Tomovska, Damien Dupin, Ren H. Bean, Timothy E. Long, Jose R. Leiza & José M. Asua. (2023) Polymer Colloids: Current Challenges, Emerging Applications, and New Developments. Macromolecules 56:7, pages 2579-2607.
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Shaghayegh Hamzehlou & José Maria Asua. 2020. Advances in Polymer Reaction Engineering. Advances in Polymer Reaction Engineering 31 57 .
Antonio Veloso, G. Patricia Leal, Amaia Agirre & José R. Leiza. (2018) Combining SEC & MALDI for characterization of the continuous phase in dispersion polymerization. European Polymer Journal 105, pages 265-273.
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Sabrina Copelli, Mario Dente, Giulia Bozzano & Marco Barozzi. (2018) Simplified modeling and main constitutive parameters estimation for industrial emulsion copolymerization processes. Chemical Engineering Journal 335, pages 988-1003.
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José M. Asua. 2018. Polymer Reaction Engineering of Dispersed Systems. Polymer Reaction Engineering of Dispersed Systems 1 22 .
Pooja Daswani & Alex van Herk. (2016) Selective Adsorption of Aqueous Phase Co‐Oligomers on Latex Particles Part 1: Influence of Different Initiator Systems. Macromolecular Theory and Simulations 26:1.
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Javier Alejandro Díaz-Ponce, Humberto Vázquez-Torres & Carlos Martínez-Vera. (2015) Emulsion terpolymerization of St/MMA/BuA: Modeling of composition, number of particles and the influence of n -DDM on the molecular weights. Chemical Engineering Science 138, pages 41-58.
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Shaghayegh Hamzehlou, Nicholas Ballard, Paula Carretero, Maria Paulis, Jose M. Asua, Yuri Reyes & Jose Ramon Leiza. (2014) Mechanistic investigation of the simultaneous addition and free-radical polymerization in batch miniemulsion droplets: Monte Carlo simulation versus experimental data in polyurethane/acrylic systems. Polymer 55:19, pages 4801-4811.
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Shaghayegh Hamzehlou, Yuri Reyes & Jose R. Leiza. (2013) Modeling the Mini-Emulsion Copolymerization of N -Butyl Acrylate with a Water-Soluble Monomer: A Monte Carlo Approach . Industrial & Engineering Chemistry Research 53:22, pages 8996-9003.
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Iñigo Calvo, Ken Hester, Jose R. Leiza & José M. Asua. (2013) Mathematical Modeling of Carboxylated SB Latexes . Macromolecular Reaction Engineering 8:4, pages 329-346.
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Iñigo Calvo, Ken Hester, José M. Asua & Jose R. Leiza. (2014) Seeded Semibatch Emulsion Copolymerization of Styrene, Butadiene, and Carboxylic Acids in a Pilot Plant Reactor. Macromolecular Reaction Engineering 8:3, pages 217-226.
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Virginia I. Rodríguez, Roque J. Minari, Diana A. Estenoz, Luis M. Gugliotta & Gregorio R. Meira. (2013) Emulsion polymerization of isoprene: Mathematical model for long-chain branching. Journal of Applied Polymer Science 127:2, pages 1038-1046.
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Pooja Daswani, Frank Rheinhold, Martin Ottink, Bastiaan Staal & Alex van Herk. (2012) Method to isolate and characterize oligomers present in the aqueous phase in emulsion copolymerization. European Polymer Journal 48:2, pages 296-308.
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Pooja Daswani & Alex van Herk. (2011) Entry in Emulsion Copolymerization: Can the Existing Models be Verified?. Macromolecular Theory and Simulations 20:8, pages 614-620.
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Alexander M. van Herk. (2009) Modeling of Emulsion Polymerization, Will It Ever be Possible ? Part-2: Determination of Basic Kinetic Data Over the Last Ten Years. Macromolecular Symposia 275-276:1, pages 120-132.
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Y.R. Mariano, E.L. Casella & Tvrzská M. de Gouvêa. (2006) PREDICTION OF RADICALS OF CRITICAL LENGTH IN EMULSION POLYMERIZATION PROCESSES. IFAC Proceedings Volumes 39:2, pages 285-290.
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José M. Asua. (2004) Emulsion polymerization: From fundamental mechanisms to process developments. Journal of Polymer Science Part A: Polymer Chemistry 42:5, pages 1025-1041.
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