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Original Articles

Mathematical Modeling of Multimonomer (Vinylic, Divinylic, Acidic) Emulsion Copolymerization Systems

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Pages 627-662 | Received 15 Oct 2002, Accepted 04 Jun 2003, Published online: 15 Feb 2007

References

  • Arzamendi , G. and Asua , J. M. 1995 . Modeling gelation and sol MWD in emulsion polymerization . Macromolecules , 28 : 7479 – 7490 .
  • Arzamendi , G. , Forcada , J. and Asua , J. M. 1994 . Kinetics of long‐chain branching in emulsion polymerization . Macromolecules , 27 : 6068 – 6079 .
  • Arzamendi , G. , Sayer , C. , Zoco , N. and Asua , J. M. 1998 . Modeling of MWD in emulsion polymerization: partial distinction approach . Polym. React. , : 193 – 223 .
  • Asua , J. M. , Sudol , E. D. and El‐Aasser , M. S. 1989 . Radical desorption in emulsion polymerization . J. Polym. Sci., A, Polym. Chem. , 27 : 3903 – 3913 .
  • Broadhead , T. O. , Hamielec , A. E. and MacGregor , J. F. 1985 . Dynamic modeling of the batch, semi‐batch and continuous production of styrene/butadiene copolymers by emulsion polymerization . Makromol. Chem., Suppl. , 10/11 : 105 – 128 .
  • Chandrasiri , J. A. and Wilkie , C. A. 1996 . Chemically initiated graft copolymerization of acrylic acid onto acrylonitrile‐butadiene‐styrene (ABS) terpolymer and its constituent polymers . J. Polym. Sci., A, Polym. Chem. , 34 : 1113 – 1120 .
  • Charmot , D. and Guillot , J. 1992 . Kinetic modeling of network formation in styrene‐butadiene emulsion copolymers: a comparative study with the generalized form of Flory's theory of gelation . Polymer , 33 : 352 – 360 .
  • Charmot , D. , D'Allest , J. F. and Dobler , F. 1996 . Carboxylated styrene‐butyl acrylate and styrene‐butadiene emulsion copolymers. Modeling the distribution of the acid monomer between serum, particle surface and the particle core . Polymer , 37 : 5237 – 5245 .
  • Chern , C. S. and Lin , C. H. 1997 . Particle nucleation in semibatch surfactant‐free emulsion polymerization of acrylic monomers . Polym. Int. , 42 : 409 – 421 .
  • Forcada , J. and Asua , J. M. 1985 . Modeling the microstructure of emulsion copolymers . J. Polym. Sci., Polym. Chem. Ed. , 23 : 1955 – 1962 .
  • Forcada , J. and Asua , J. M. 1990 . Modeling of unseeded emulsion copolymerization of styrene and methyl methacrylate . J. Polym. Sci., A, Polym. Chem. , 28 : 987 – 1009 .
  • Ghielmi , A. , Fiorentino , S. , Storti , G. and Morbidelli , M. J. 1997 . Long‐chain branching in emulsion polymerization . J. Polym. Sci., A, Polym. Chem. , 35 : 827 – 858 .
  • Gugliotta , L. M. , Brandolini , M. C. , Vega , J. R. , Iturralde , E. O. , Azum , J. L. and Meira , G. 1995 . Dynamic model of a continuous emulsion copolymerization of styrene and butadiene . Polym. React. Eng. , 3 : 201 – 233 .
  • Lange , D. M.Ph.D. 1991 . “ Emulsion copolymerization with functional monomers in continuous reactors ” . In Dissertation School of Chemical Engineering, Georgia Institute of Technology .
  • Lange , D. M. and Poehlein , G. W. 1993 . Modeling of styrene‐carboxylic acid monomer emulsion copolymerization in a series of seed‐fed continuous stirred tank reactors . Polym. React. Eng. , 1 : 41 – 73 .
  • Maxwell , I. A. , Morrison , B. R. , Napper , D. H. and Gilbert , R. G. 1991 . Entry of free radicals into latex particles in emulsion polymerization . Macromolecules , 24 : 1629 – 1640 .
  • Mestach , D. E. and Baan , W. H. 1995 . Emulsion polymerization of carboxylated polybutyl methacrylate microparticles—modeling and experimental verification . Dechema Monographien , 131 : 35 – 44 .
  • Nomura , M. 1982 . Emulsion Polymerization Edited by: Piirma , I. 191 New York : Academic Press .
  • Nys , G. G. and Rekker , R. F. 1973 . Statistical analysis of a series of partition coefficients with special reference to the predictability of folding of drug molecules. Introduction of hydrophobic fragmental constants (f values) . Chim. Ther. , 8 : 521 – 535 .
  • Omi , S. , Kushibiki , K. , Negishi , M. and Iso , M. 1985 . Generalized computer modeling of semibatch n‐component emulsion copolymerization system and its applications . Zairyo Gijutsu , 3 : 426 – 441 .
  • Plessis , C. , Arzamendi , G. , Leiza , J. R. , Schonbrood , H. A.S. , Charmot , D. and Asua , J. M. 2001 . Modeling of seeded semibatch emulsion polymerization of n‐BA . Ind. Eng. Chem. Res. , 40 : 3883 – 3894 .
  • Poehlein , G. W. 1995 . Emulsion polymerization with water soluble monomers in batch and continuous reactors . Macromol. Symp. , 92 : 179 – 194 .
  • Richards , J. R. , Congalidis , J. P. and Gilbert , R. G. 1989 . Mathematical modeling of emulsion copolymerization reactors . J. Appl. Polym. Sci. , 37 : 2727 – 2756 .
  • Rigdahl , M. , Lason , L. , Hagen , R. , Karlsson , O. and Wesslen , B. 1997 . Heterogeneous latexes as binders in porous particle structures . J. Appl. Polym. Sci. , 63 : 661 – 670 .
  • Rosen , M. J. 1989 . Surfactant and Interfacial Phenomena , 2nd ed. New York : John Wiley & Sons . 122, 215
  • Saidel , G. M. and Katz , S. 1968 . Dynamic analysis of branching in radical polymerization . J. Polym. Sci., Polym. Phys. , 6 : 1149 – 1160 .
  • Shoaf , G. L. and Poehlein , G. W. 1991 . Kinetics of emulsion copolymerization with acrylic acids . J. Appl. Polym. Sci. , 42 : 1213 – 1237 .
  • Smoluchowsky , M. V. 1917 . Mathematical modeling of the kinetics of the coagulation of colloidal solutions . Zeitschrift Physik. Chem. , 92 : 129 – 168 .
  • Teymour , F. and Campbell , J. D. 1992 . Numerical fractionation—a novel technique for the mathematical modeling of long‐chain branching and crosslinking in polymer systems . Dechema Monographien , 127 : 149 – 157 .
  • Teymour , F. and Campbell , J. D. 1994 . Analysis of the dynamics of gelation in polymerization reactors using the “numerical fractionation” technique . Macromolecules , 27 : 2460 – 2469 .
  • Tobita , H. and Hamielec , A. E. 1988 . A kinetic model for network formation in free radical polymerization . Makromol. Chem., Macromol. Symp. , 20/21 : 501 – 543 .
  • Tobita , H. and Hamielec , A. E. 1989 . Modeling of network formation in free radical polymerization . Macromolecules , 22 : 3098 – 3105 .
  • Tobita , H. and Hamielec , A. E. 1990 . Modeling emulsion copolymerization crosslinking kinetics . Makromol. Chem., Macromol. Symp. , 35/36 : 193 – 212 .
  • Tobita , H. , Takada , Y. and Nomura , M. 1994 . Molecular weight distribution in emulsion polymerization . Macromolecules , 27 : 3804 – 3811 .
  • Urretabizkaia , A. , Arzamendi , G. and Asua , J. M. 1992 . Modeling semicontinuous emulsion terpolymerization . Chem. Eng. Sci. , 47 : 2579 – 2584 .
  • Vega , J. R. , Gugliotta , L. M. , Bielsa , R. , Brandolini , M. C. and Meira , G. R. 1997 . Emulsion copolymerization of acrylonitrile and butadiene. Mathematical model of an industrial reactor . Ind. Eng. Chem. , 36 : 1238 – 1246 .
  • Verdurmen , E. M. , Geurts , J. M. , Verstegen , J. M. , Maxwell , I. A. and German , A. L. 1993 . Seeded emulsion polymerization of butadiene. 2. Effects of persulfate and tert‐dodecyl mercaptan . Macromolecules , 26 : 6289 – 6298 .
  • Yalkowsky , S. H. and Banerjee , S. 1992 . Aqueous Solubility. Methods of Estimation for Organic Compounds 127 New York : Marcel Dekker .
  • Yuan , X. Y. , Dimonie , V. L. , Sudol , E. D. , Roberts , J. E. and El‐Aasser , M. S. 2002 . Toward an understanding of the role of water‐soluble oligomers in the emulsion polymerization of styrene‐butadiene‐acrylic acid. Mechanisms of water‐soluble oligomer formation . Macromolecules , 35 : 8356 – 8370 .
  • Zhou , Z. F. , Huang , H. and Liu , N. C. 2002 . Kinetics and mechanism of grafting of crotonic acid onto acrylonitrile‐butadiene‐styrene terpolymer . J. Appl. Polym. Sci. , 85 : 726 – 733 .

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